Product ID:EPON CURING AGENT H-2, 43631
MSDS Date:10/18/1991
FSC:8040
NIIN:00N024213
MSDS Number: BNCQV

SHELL OIL CO

HOUSTON, TX 77210
US

Emergency Phone: 713-473-9461;800-424-9300(CHEMTREC)

Info Phone: 713-424-4819

Preparer: G.A. VAN GELDER

Cage: SHELO

SHELL OIL COMPANY

4320 HOUSTON, TX 77210 US

Telephone: 800-231-6950

Cage: 54527

OCCURS SPONT, KEEP HEAD BELOW HIPS TO PVNT ASPIR OF

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THAN 2.0 ML PER KG HAS BEEN INGEST & VOMIT HAS NOT

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VICTIM'S HEAD BELOW HIPS TO PVNT ASPIR. IF SYMP

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BEFORE EMESIS, GASTRIC LAVAGE USING CUFFED

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RESIDUE W/ABSORB SUCH AS CLAY, SAND, OR OTHER

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TIGHTLY FOR PROPER DISP. FLUSH AREA W/H*2O TO

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TAKE UP WITH AN ABSORBENT MATERIAL AND

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CNTNRS. DO NOT PRESS DRUM CNTNRS TO EMPTY THEM.

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THAT HAVE BEEN EMPTIED, CAN CONT HAZ PROD RESIDUES.

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APPLYING COSMETICS, OR USING TOILET FACILITIES.

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AND OTHER PROT EQUIP AFTER EACH USE. DESTROY

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(ORAL,RAT) 1660 MG/KG. MIXTURE

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Fraction By Weight: 100%

ETHYLENEDIAMINE/METHYL ISOBUTYL KETONE KETIMINE

CAS: 25707-70-4

Fraction By Weight: 97-98%

(ORAL,RAT) 1.16

CAS: 107-15-3

RTECS: KH8575000

Fraction By Weight: 2-3%

OSHA PEL 10 PPM

ACGIH TLV: 10 PPM, S

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

COMPONENT #3, PROD AS MIST/VAPS MAY BE EXTREMELY

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INFLAM INCL LUNG; EXTREME CASES MAY BE FATAL.

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SWALLOWED; MAY PRDCE GASTROINTESTINAL TRACT

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BY LOSS OF APPETITE, JAUNDICE (YELLOWISH SKIN

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& KIDNEY FUNCTIONS FROM PREEXISTING

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CANNOT BE DECONTAM & SHD BE DESTROYED TO

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O*2 IF BRTHG IS DFCLT. GIVE ARTF RESP IF NOT BRTHG.

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LD50 LC50 Mixture:SEE INGREDIENT 1 & 3.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE: BASED ON PROD TESTING PROD IS
CORR TO EYES & MAY CAUSE SEV DMG INCL BLINDNESS. SKIN: BASED ON
PROD TESTING PROD IS CORR TO SKIN. BASED ON PRESENCE OF COMPONENT
#3, PROD MAY CAUSE SKIN SENSIT. INH AL: BASED ON PRESENCE OF
COMPONENT #3, PROD MAY BE POTENTIAL RESP SENSIT IF CNDTNS GEN
VAP/MISTS. BASED ON (ING 4)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:IRRIT AS NOTED ABOVE. SKIN SENSIT (ALLERGY) MAY
BE EVIDENCED BY RASHES, ESPEC HIVES. LUNG SENSIT (E.G., ALLERGY,
ASTHMA) MAY BE EVIDENCED BY WHEEZING W/SHORT OF BRTHG & COUGH.
KIDNEY DMG MAY BE EVIDEN CED BY CHANGES IN URINE OUTPUT, URINE
APPEAR/EDEMA (SWELLING FROM FLUID RETENTION). LIVER DMG MAY BE
EVIDENCED (ING 7)
Medical Cond Aggravated by Exposure:PREEXISTING EYE, SKIN & RESP
DISORDERS MAY BE AGGRAVATED BY EXPOS TO PROD. PREEXISTING SKIN/LUNG
ALLERGIES MAY INCR CHANCE OF DEVELOPING INCR ALLERGY SYMP FROM
EXPOS TO PROD. IMPAIRED LIVER (ING 8)

First Aid:EYE: IMMED FLUSH EYES W/PLENTY OF H*2O FOR AT LEAST 15 MIN
WHILE HOLDING EYELIDS OPEN. RINSE CONT W/H*2O WHILE ON WAY TO GET
MED ATTN. SKIN: IMMED REMOVE CONTAM CLTHG/SHOES. WIPE EXCESS FROM
SKIN & FL USH W/PLENTY OF H*2O FOR AT LEAST 15 MIN. USE SOAP IF
READILY AVAIL, OR FOLLOW BY THORO WASHING W/SOAP & H*2O. DO NOT
REUSE CLTHG UNTIL THORO DECONTAM. CONTAM LEATHER ARTICLES, INCL
SHOES, (ING 9)

Flash Point Method:PMCC
Flash Point:135F,57C
Extinguishing Media:USE H*2O FOG, FOAM, DRY CHEM/CO*2. DO NOT USE
DIRECT STREAM OF H*2O.PROD WILL FLOAT & CAN BE REIGNITED ON SURF OF
H*2O.
Fire Fighting Procedures:CAUTION. COMBUST.DO NOT ENTER CONFINED FIRE
SPACE W/OUT FULL BUNKER GEAR (HELMET W/FACE SHLD, BUNKER
COATS,GLOVE & RUB BOOTS), INCL NIOSH/MSHA APPRVD(SUPP DATA)
Unusual Fire/Explosion Hazard:H*2O DECOMP PROD TO GIVE IRRIT
ETHYLENEDIAMINE & FLAM METHYL ISOBUTYL KETONE (MIBK). HEAT &/OR
COMBUST CAN GEN TOX VAPS & FUMES. HNDL AS COMBUST LIQ.(SUPP DATA)

Spill Release Procedures:CAUTION. COMBUST. LRG SPILLS: ELIM POTENTIAL
SOURCES OF IGNIT. WEAR APPROP NIOSH/MSHA APPRVD RESP & OTHER PROT
CLTHG. SHUT OFF SOURCE OF LEAK ONLY IF SAFE TO DO SO. DIKE & CONT.
REMOVE W/VACUUM TRUCKS /PUMP TO STORAGE/SALVAGE VESSELS. SOAK UP
(ING 15)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:CAUTION. COMBUST LIQ. KEEP LIQ & VAP
AWAY FROM HEAT, SPARKS & FLAME. SURFS THAT ARE SUFF HOT MAY IGNITE
EVEN LIQ PROD IN ABSENCE OF SPARKS OR FLAME.
Other Precautions:EXTING PILOT LIGHTS, CIGARETTES & TURN OFF OTHER
SOURCES OF IGNIT PRIOR TO USE & UNTIL ALL VAPS ARE GONE. CNTNRS,
EVEN THOSE THAT HAVE BEEN EMPTIED. CAN CONT EXPLO VAPS. DO NOT CUT,
DRILL, GRIND, WELD /PERFORM SIMILAR OPER ON/NEAR (ING 18)

Respiratory Protection:IF EXPOS MAY/DOES EXCEED OCCUPATIONAL EXPOSURE
LIMITS USE A NIOSH/MSHA APPROVED RESP TO PREVENT OVEREXPOSURE. IN
ACCORD WITH 29 CFR 1910.134 USE EITHER A NIOSH/MSHA APPROVED
FULL-FACE, ATMOSPHERE-SUPP RESP/AIR-PURIFYING RESP FOR ORG VAPS.
Ventilation:USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL
VAPOR CONCENTRATIONS.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:CHEM WORK GOG & FULL LGTH FACESHLD
Other Protective Equipment:CHEM-RESIST PROT OUTER CLTHG/APRON,
OVERSHOES& FACESHLD SUITABLE FOR POTENTIAL EXPOS.EYE WASH FOUNTAIN
& SAFETY SHOWERS.
Work Hygienic Practices:AVOID BREATHING VAPOR OR MIST. DO NOT GET IN
EYES. DO NOT GET ON SKIN OR CLOTHING.
Supplemental Safety and Health
FIRE FIGHT PROC: POS PRESS SCBA. COOL FIRE EXPOS CNTNRS W/H*2O. EXPLO
HAZ: CNTNRS EXPOS TO INTENSE HEAT FROM FIRES SHD BE COOLED W/H*2O
TO PVNT VAP PRESS BUILDUP WHICH COULD RSLT IN CNTNR RUPTURE. CNT NR
AREAS EXPOS TO DIRECT FLAME CONT SHDBE COOLED W/LRG QTYS OF H*2O AS
NEEDED TO PVNT WEAK OF CNTNR STRUCTURE.

HCC:F4
Vapor Pres:<1
Vapor Density:>1
Spec Gravity:0.86
Solubility in Water:SLIGHT
Appearance and Odor:PALE YELLOW LIQUID; AMMONICAL ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID HEAT, FLAME, H*2O, INCL ATMOSPHERIC
MOISTURE. CONSIDERABLE HEAT RELS IS OBTAINED IN CURING OF SOME
EPOXY RESINS.
Hazardous Decomposition Products:BY HYDROLYSIS: MIBK & ETHYLENEDIAMINE.
NITROGEN OXIDES, CO AND UNIDENTIFIED ORGANIC CMPDS MAY BE FORMED
DURING COMBUST.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE,
AND LOCAL REGULATIONS .

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